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袁相爱博士

信息来源: 发布日期: 2016-11-10 浏览次数: 5927


 

袁相爱,女,副教授;南京大学物理化学博士,主要研究方向为材料光学性质的理论研究,光催化反应及过渡金属催化反应机理研究。近几年在Nature Chemistry, Nature Communication, Angew, J.Mater.Chem,C, J. Phys. Chem. B., J. Phys. Chem. A., Org. Lett., Adv. Synth. Catal., Chem. Eur. J.等期刊发表论文四十多篇。主持国家自然科学基金青年基金1项,主持山东省自然科学基金一项,主持校级项目1项。参与多项国家和省级项目。

教育背景:

       1. 2012.9-2016.9,南京大学,物理化学,博士;

2. 2002.9-2005.7,南京师范大学,应用化学,硕士;

3. 1998.9-2002.6,曲阜师范大学,化学工程与工艺,学士。

主讲课程:

《化学工程基础》、《化工仪表及自动化》、《化学工艺学》、化工基础/原理实验

主持项目:

1.国家自然科学基金青年项目,217031182018/1/1-2020/12/3125万,已结题,主持。

2.山东省自然科学基金面上项目,ZR2017MB038 2017/8-2020/615万,已结题,主持。

3 曲阜师范大学校级项目,XJ201102011/8-2014/80.6万元,已结题,主持。

招生:硕士:1-2/年,招生专业:物理化学

实验室化学楼301

Emailxiang_aiyuan@126.com, 154470762@qq.com


欢迎感兴趣的本科生和研究生加入袁相爱课题组!


发表学术论文:

44. Xu Shen; Congcong Huang; Xiang-Ai Yuan*, Shouyun Yu*Diastereoselective and Stereodivergent Synthesis of 2-Cinnamylpyrrolines Enabled by Photoredox-Catalyzed Iminoalkenylation of Alkenes, Angewandte Chemie International Edition, 2021, 60, 9672-9679.

43. Liying Mu; Wenjing Fan; Xiang-Ai Yuan*; Congcong Huang; Dan Li; Siwei Bi*; Mechanistic insights into the C(sp3)-H heteroarylation of amides and Fukui function analysis of regioselectivity, Molecular Catalysis, 2021, 502111394.

42. Jie Dong#, Xiang-Ai Yuan#, Zhongfei Yan#, Liying Mu#, Junyang Ma, Chengjian Zhu, Jin Xie*, Manganese-catalysed divergent silylation of alkenes, Nature Chemistry. 2021. 13, 182-190.

41. Dongping Wang, Jie Dong, Wenjing Fan, Xiang-Ai Yuan, Jian Han, Jin Xie*, Dimeric Manganese-Catalyzed Hydroarylation and Hydroalkenylation of Unsaturated Amides, Angewandte Chemie International Edition, 2020, 59(22)8430-8434.

40. Yubo Pang, Gengtu Liu, Congcong Huang, Xiang-Ai Yuan, Weipeng Li, Jin Xie*, A Highly Efficient Dimeric Manganese-Catalyzed Selective Hydroarylation of Internal Alkynes, Angewandte Chemie International Edition, 2020, 59(31)12789-12794.

39. Yichun Chu , Siwei Bi *, Xiaohan Wu , YuanYe Jiang , Yuxia Liu , Baoping Ling , Xiang-Ai Yuan, Mechanism, bonding nature of metal-nitrenoid, and selectivity for a nitrene-participating three-component carboamination of dienes: A DFT study Molecular Catalysis, 2020, 497111222.

38. Mingxiao, Shao, Xicheng, Liu*, Yiwei, Sun, Shuaihua, Dou, Qi, Chen, Xiang-Ai, Yuan, Laijin, Tian, Zhe, Liu*, Preparation and the anticancer mechanism of configuration-controlled Fe(II)–Ir(III) heteronuclear metal complexes, Dalton Transactions, 2020, 4912599-12609.

37. Xicheng Liu*, Shujiao Chen, Xingxing Ge, Ying Zhang, Yaoqi Xie, Yingying Hao, Daiqun Wu, Jinmin Zhao, Xiang-Ai Yuan, Laijin Tian, Zhe Liu*, Dual functions of iridium(III) 2-phenylpyridine complexes: Metastasis inhibition and lysosomal damage, Journal of Inorganic Biochemistry, 2020, 205110983.

36. Hui Chen, Wenjing Fan, Xiang-Ai Yuan*; Shouyun Yu,* Site-selective remote C(sp(3))-H heteroarylation of amides via organic photoredox catalysis, Nature Communications, 2019, 104743.

35. Muliang Zhang, Xiang-Ai Yuan, Chengjian Zhu, Jin Xie*, Deoxygenative Deuteration of Carboxylic Acids with D2O, Angewandte Chemie International Edition, 2019, 58(1)312-316.

34. Xingxing Ge, Xicheng Liu*, Zhenzhen Tian, Shujiao Chen, Xinyu Liu, Lihua Guo, Peiwei Gong, Baoping Ling, Xiang-Ai Yuan, Zhe Liu*, Half-sandwich Ruthenium (II) complexes with triphenylamine modified dipyridine skeleton and application in biology/luminescence imaging, Applied Organometallic Chemistry, 2019, 33(11)e5171.

33. Xicheng Liu*, Xiangdong He, Xiaojing Zhang, Yongling Wang, Jiaying Liu, Xiujuan Hao, Yue Zhang, Xiang-Ai Yuan, Laijin Tian,; Zhe Liu*, New Organometallic Tetraphenylethylene.Iridium(III) Complexes with Antineoplastic Activity, ChemBioChem, 2019, 20(21)2767-2776.

32. Xingxing Ge, Shujiao Chen, Xicheng Liu,* Qinghui Wang, Lijun Gao, Chengfeng Zhao, Lei Zhang, Mingxiao Shao, Xiang-Ai Yuan, Laijin Tian, Zhe Liu*, Ferrocene-Appended Iridium(III) Complexes: Configuration Regulation, Anticancer Application, and Mechanism Research, Inorganic Chemistry, 2019, 58(20)14175-14184.

31. Dai Zeng#, Xiang-Ai Yuan#, Jing-Cui Liu, Li Li, Lu-Ping Wang, Ming-Feng Qin, Song-Song Bao, Jing Ma*, Li-Min Zheng*, Cyclometalated Iridium(III) Complexes Incorporating Aromatic Phosphonate Ligands: Syntheses, Structures, and Tunable Optical Properties, ACS Omega, 2019, 4(15)16543-16550.

30. Peiwei Gong, Lei Zhang, Xiang-Ai Yuan, Xicheng Liu, Xiuli Diao, Qiao Zhao, Zhenzhen Tian, Jing Sun, Zhe Liu* Jinmao You, Multifunctional fluorescent PEGylated fluorinated graphene for targeted drug delivery: An experiment and DFT study, Dyes and Pigments, 2019, 162573-582.

29. Rehanguli Ruzi, Junyang Ma, Xiang-Ai Yuan, Wenliang Wang, Shanshan Wang, Muliang Zhang, Jie Dai, Jin Xie*, Chengjian Zhu*, Deoxygenative Arylation of Carboxylic Acids by Aryl Migration, Chemistry–A European Journal, 2019, 25(55)12724-12729.

28. Juanjuan Li, Xicheng Liu,* Haifeng Zhang, Xingxing Ge, Yanhua Tang, Zhishan Xu,Laijin Tian, Xiangai Yuan, Xudong Mao, and Zhe Liu*, Ferrocenyl-Triphenyltin Complexes as Lysosome-Targeted Imaging and Anticancer Agents, Inorganic Chemistry, 2019, 581710-1718.

27. Xiang-Ai Yuan, Meng-Na Yu, Qiang Zhu, Wan-Wan Zhang, Ling-Hai Xie*, Wei Huang, Jing Ma*, Synergistic steric pairing effects of terfluorenes with ternary side groups on beta-conformation transition: experiments and computations, Journal of Materials Chemistry C, 2018, 6(6)1551-1561.

26. Xiang-Ai Yuan, Jin Wen, Dong Zheng, Jing Ma*, Simulations of absorption spectra of conjugated oligomers: role of planar conformation and aggregation in condensed phase, Molecular Physics, 2018, 116(7-8)910-926.

25. Dong Zheng, Xiang-Ai Yuan, Haibo Ma, Xiaoxiong Li, Xizhang Wang, Ziteng Liu, Jing Ma*, Unexpected solvent effects on the UV/Vis absorption spectra of o-cresol in toluene and benzene: in contrast with non-aromatic solvents, Royal Society Open Science, 2018, 5(3)171928.

24. Nengneng Zhou, Xiang-Ai Yuan, Yue Zhao, Jin Xie*, Chengjian Zhu*, Synergistic Photoredox Catalysis and Organocatalysis for Inverse Hydroboration of Imines, Angewandte Chemie International Edition, 2018, 57(15)3990-3994.

23. Zhongfei Yan, Xiang-Ai Yuan, Yue Zhao, Chengjian Zhu, Jin Xie*, Selective Hydroarylation of 1,3-Diynes Using a Dimeric Manganese Catalyst: Modular Synthesis of Z-Enynes, Angewandte Chemie International Edition, 2018, 57(39)12906-12910.

22. Wentao Xu, Junyang Ma, Xiang-Ai Yuan, Jie Dai, Jin Xie*, Chengjian Zhu*, Synergistic Catalysis for the Umpolung Trifluoromethylthiolation of Tertiary Ethers, Angewandte Chemie International Edition, 2018, 57(32)10357-10361.

21. Jing Shi, Siwei Bi*, Yuanye Jiang, Yuxia Liu, Baoping Ling, Xiang-Ai Yuan, A DFT mechanistic study on gold(I)-catalyzed cascade reaction of aminaloalkyne involving Petasis-Ferrier cyclization, Journal of Organometallic Chemistry, 2018, 864136-142.

20. Siwei Bi*, Peng Liu, Baoping Ling, Yuan Xiangai; Yuanye Jiang*, Mechanism of N-to-S acyl transfer of N-(2-hydroxybenzyl) cysteine derivatives and origin of phenol acceleration effect, Chinese Chemical Letters, 2018, 29(8)1264-1268.

19. Guojing, Pei, Yuxia, Liu*, Guang, Chen, Xiangai, Yuan,Yuan-Ye, Jiang, Siwei Bi*,Unveiling the mechanisms and secrets of chemoselectivities in Au(i)-catalyzed diazo-based couplings with aryl unsaturated aliphatic alcohols, Catalysis Science & Technology, 2018, 8(17)4450-4462.

18. Siwei Bi, Peng Liu, Baoping Ling, Xiangai Yuan, Yuanye Jiang, Mechanism of N-to-S acyl transfer of N-(2-hydroxybenzyl) cysteine derivatives and origin of phenol acceleration effect, Chinese Chemical Letters, 2018, 29, 1264-1268.

17. Weizhi Li, Xiangai Yuan, Jin Huang, Bang'an Peng, Feng Zhou, Jing Ma, Xudong Jia, “synthesis of heat resistant benzoxazine based polyfluorene and its reversible temperature sensitive fluorescence” Polymer, 2017, 109: 126-136.

16. Xiangai Yuan, Wenmin Wang, ZiqiTian, Siwei Bi, Jing Ma, “Electron-Donating Groups and High Ring Strain Promoted Ring Opening of Methylenecyclopropanes Catalyzed by Rhodium and Iridium Complexes, J. Organometa. Chem.201681129-39

15. Xiangai Yuan, Dong Zheng, Xiaoxiong Li, Pingying Liu, Jing Ma, Effects of Intra- and Intermolecular Hydrogen Bonding Interactions on Infrared Spectroscopy and UV/vis absorption spectra of O-Cresol Aqueous Solutions: a Combined MD/TD-DFT and Experimental Study J. Phys. Chem. A. 201612010196-10206.

14. Dong Zheng, Xiangai Yuan, Jing Ma, Rationalization of pH-dependent Absorption Spectrum of o-Methyl Red in Aqueous Solutions: TDDFT Calculations and Experiments, Acta Physico-Chimica Sinica. 2016, 32, 290-300.

13. Xiangai Yuan, Wanwan Zhang, Ling-Hai Xie, Jing Ma, Wei Huang, Wenjian Liu, Role of Planar Conformations in Aggregation Induced Spectral Shifts of Supermolecular Oligofluorenols in Solutions and Films: A Combined Experimental and MD/TD-DFT Study J. Phys. Chem. B, 2015, 119, 10316-10333.

12. Yuanzheng Cheng, Xiangai Yuan, Jing Ma, Shouyun Yu. Direct Aromatic CH Trifluoromethylation via an Electron-Donor– Acceptor Complex, Chem. Eur. J. 2015, 21, 1-6.

11. Ziqi Tian, Yuanjing Xiao, Xiangai Yuan, Zuliang Chen, Junliang Zhang, Jing Ma Control of Chemoselectivity by Coordinated Water and Relative Size of Ligands to Metal Cations of Lewis Acid Catalysts for Cycloaddition of an Oxirane Derivative to an Aldehyde: Theoretical and Experimental Study, Organometallics. 2014, 33, 1715-1725.

10. Yuanzheng Cheng, Xiangai Yuan, Heng Jiang, Ruzhi Wang, Jing Ma, Yan Zhang, ShouyunYu. Regiospecific Synthesis of 1-Trifluoromethylisoquinolines Enabled by PhotoredoxSomophilic Vinyl Isocyanide Insertion, Adv. Synth. Catal. 2014, 356, 2859-2866.

9. Jin Xie, Xiangai Yuan, AblimitAbdukader, Chengjian Zhu, Jing Ma. Visible-light-promoted radical C–H trifluoromethylation of free anilines, Org. Lett. 2014, 16, 1768-1771.

8. Journal of Organometallic Chemistry, 20106951682-1687,

7. Journal of Organometallic Chemistry, 20106951576-1582

6. Journal of Organometallic Chemistry, 2010695552-557

5. 无机化学快报, 201228551-559

4. Chinese Chemical Letters, doi/10.1016/j.cclet.2017.11.043

3. Journal of Theoretical and Computational Chemis, 2010999-107

2. Journal of Molecular Structure: Theochem, 2008, 848, 47-55

1. Journal of Theoretical and Computational Chemis, 2011131-40