郭丽华博士简介

发布时间:2015-10-08文章来源:暂无 浏览次数:

 

个人简历:

郭丽华,男,19829月生,山东嘉祥人。现为曲阜师范大学化学与化工学院副教授,硕士生导师。负责《高分子化学》、《材料化学实验》、《现代高分子化学》(研究生)等理论和实验课程的讲授,在核心期刊(高分子通报、化学教育、大学化学)发表第一及通讯作者教学论文14篇。主持校级教改项目3项,指导大学创新创业训练项目6项。科研上发表SCI论文60余篇(基本为二区以上,H因子28),第一及通讯作者论文45篇。其中7篇为ESI被引论文或ESI热点论文。第一发明人申请发明专利11项(已授权9项)。主持完成国家自然科学青年基金、山东省优秀中青年科学家科研奖励基金、山东省自然科学基金面上项目和聚合物复合材料及功能材料教育部重点实验室开放课题等项目,山东省高等学校青创人才引育计划立项建设团队负责人。主持完成校级科研项目2

联系方式:Emailguolihua-qfnu@139.com guolihua@qfnu.edu.cn  0537-4455129

课题组网站:https://www.x-mol.com/groups/guo_lihua

教育背景及经历:

2001-2005年,青岛科技大学高分子科学与工程学院 高分子材料与工程/英语 工学/文学学士。

2005-2010年,中山大学高分子研究所 高分子化学与物理 理学博士。

2010-2017年, 曲阜师范大学化学与化工学院,讲师。

2014-2015年, 中国科学技术大学高分子科学与工程系访学。

201712月至今,曲阜师范大学化学与化工学院,副教授。

2019-2020年,美国科罗拉多州立大学访学。

研究方向:

1、烯烃聚合催化剂设计及新型高分子材料的合成

2、金属有机配合物抗癌药物的设计与合成

入职以来教学论文:

理论课教学论文:

1郭丽华*。“高分子化学”的情境化教学,化学教育2017,382,20-23.

2郭丽华*,郭道军等。地方师范院校材料化学专业课程体系的构建与实践,化学教育2017,3818,10-13

3郭丽华*,徐衍建等。乳液聚合中两种推导聚合度公式的方法对比,化学教育2018,398,17-18

4郭丽华*,孔文瑜等。“配位聚合”教学内容的整合,大学化学2018,334,69-73

5郭丽华*,刘文静等。气态单体活性聚合动力学-“活性聚合教学内容的补充,化学教育2018,3924,25-27

6郭丽华*。关于活性聚合判据的讨论,大学化学2019342,61-64

7郭丽华*。区分无规及嵌段共聚物与混合均聚物的方法,高分子通报20213924,25-27

8纪明君(本科生), 郭丽华*(通讯)等。关于五元环内酯开环反应性的商榷,化学教育2021,4210,95-98

实验课教学论文:

9郭丽华*。界面缩聚合成尼龙实验的综合性改进,化学教育2016,3720,35-37

10郭丽华*,荆鑫瑜。苯乙烯本体聚合反应动力学实验的改造与拓展,化学教育2017,388,36-38

11郭丽华*,刘燕兰等。核磁共振法测定自由基共聚合竞聚率综合实验的设计,化学教育2017,3816,38-40

12刘文静(本科生), 郭丽华*(通讯)等。过渡金属配合物催化异戊二烯配位聚合综合实验的设计,化学教育2018,39(10),39-43

13孔文瑜(本科生), 郭丽华*(通讯)等。乙烯气相配位聚合综合实验的设计,化学教育2019,408,38-41

入职以来科研论文(第一或通讯)及专利:

论文:

2022

45Hu X. Y.; Guo L. H. * (通讯); Liu M. Q.; Sun M. R.; Zhang Q. Y.; Peng H. W.; Zhang F. J.; Liu Z.* Formation of Iridium(III) and Rhodium(III) Amine, Imine, and Amido Complexes Based on Pyridine-Amine Ligands: Structural Diversity Arising from Reaction Conditions, Substituent Variation, and Metal Centers. Inorg. Chem. 2022, Doi.org/10.1021/acs.inorgchem.2c00984.

44Guo L. H. * (通讯); Chen, W. Q.; Wang W. J.; An W. Y.; Gao S. N.; Zhao Y.; Luo M. L.; He G. S.; Liu T. T. Ortho-substituent Effect on Metal Coordination Geometry, Chain Microstructure and Polymer Properties in α-Diimine Nickel-catalyzed Long Chain α-Olefin Polymerization. J. Catal. 2022, 413, 8-19.

2021

43Gao J.; Guo L. H. * (通讯); Wu Y. T.; Cheng Y. H.; Hu X. Y.; Liu J. F.; Liu Z.* 16-Electron Half-Sandwich Rhodium(III), Iridium(III) and Ruthenium(II) Complexes as Lysosome-Targeted Anticancer Agents. Organometallics 2021, 40, 3999-4010.

42Guo L. H. * (通讯); Hu, X. Y.; Yang Y. J.; An W. Y.; Gao J.; Liu Qin.; Liu Z. * Synthesis and Biological Evaluation of Zwitterionic Half-Sandwich Rhodium(III) and Ruthenium(II) Organometallic Complexes. Bioorg. Chem. 2021, 116, 105311.

41Guo L. H. * (通讯); Hu, X. Y.; Lu W. Q.; Xu G. Y.; Liu Q.; Dai S. Y. * Investigations of Ligand Backbone Effects on Bulky Diarylmethyl-based Nickel(II) and Palladium(II) Catalyzed Ethylene Polymerization and Copolymerization. J. Organomet. Chem. 2021, 952, 122046.

40Yang Y. J.; Guo L. H. * (通讯); Huang J.*; Ji M. J.; Ge X. X.; Chen W. J.; Zhou H. X.; Li X.; Tuo S. J.; Liu Z.*  Fortuitous Synthesis of Unsaturated Half-sandwich Ruthenium(II) Complexes via Solvent-involved Rearrangement and Their Biological Evaluation. Dyes and Pigments 2021, 184, 108867.

39Ji, M. J.(本科生); Wu, M. Q.; Han, J. Y.; Zhang, F. J.; Peng, H. W. *; Guo L. H. * (通讯) The Recent Advances in Organocatalytic Ring-Opening Polymerization. Curr. Org. Chem. 2021, 25, 272-286. (Invited Review

38Peng, H. W.; Li, S. K.; Li, G.; Dai, S. Y. *; Ji, M. J.; Liu, Z.; Guo L. H. * (通讯) Rotation-Restricted Strategy to Synthesize High Molecular Weight Polyethylene Using Iminopyridyl Nickel and Palladium Catalyst. Appl. Organometal. Chem. 2021, 35: e6140.

2020

37 Yang Y. J.; Guo L. H. * (通讯); Ge X. X.; Chen W. J.; Zhou H. X.; Zhu T.; Li X.; Tuo S. J.; Liu Z.* Fluorescent Zwitterionic Iridium(III) Complexes Containing Sulfonate Groups: Synthesis, Biological Activity and Tracking in Live Cells. Dyes and Pigments 2020, 176, 108220.

36Yang Y. J.; Guo L. H. * (通讯); Ge X. X.; Zhu T.; Chen W. J.; Zhou H. X.; Zhao L. P.; Liu Z.* The Fluorine Effect in Zwitterionic Half-Sandwich Iridium(III)  Anticancer Complexes. Inorg. Chem. 2020, 59, 748-758.

35Dai, S. Y. *; Li, S. K.; Xu, G. Y.; Wu, C.; Liao, Y. D. *; Guo L. H. * (通讯) Flexible Cycloalkyl Substituents in Insertion Polymerization with α-Diimine Nickel and Palladium Species. Polymer Chemistry 2020, 11, 1393-1400.

2019

34Guo, L. H.; Sun, W. T.; Li, S. K.; Xu, G. Y.; Dai, S. Y. * Bulky Yet Flexible Substituents in Insertion Polymerization with α-Diimine Nickel and Palladium Systems. Polymer Chemistry 2019, 10, 4866-4871.

33Guo, L. H.; Li, S. K.; Ji, M. J.; Sun, W. T.; Liu, W. J.; Li, G.; Zhang, J. W.; Liu, Z.; Dai, S. Y. * Monoligated vs Bisligated Effect in Iminopyridyl Nickel Catalyzed Ethylene Polymerization. Organometallics 2019, 38, 2800-2806.

32Du Q.; Guo L. H. * (通讯); Ge X. X.; Zhao L. P.; Tian Z. Z.; Liu X. C.; Zhang F. J.; Liu Z.* Serendipitous Synthesis of Five-coordinated Half-sandwich Aminoimine Iridium(III) and Ruthenium(II) Complexes and Their Application as Potent Anticancer Agents. Inorg. Chem. 2019, 58, 5956-5965.

31Yang Y. L.; Guo L. H. * (通讯); Tian Z. Z.; Ge X. X.; Gong Y. T.; Zheng H. M.; Zhang S. P.; Liu Z.* Lysosome-Targeted Phosphine-Imine Half-Sandwich Iridium(III) Anticancer Complexes: Synthesis, Characterization and Biological Activity. Organometallics 2019, 38, 1761-1769.

30Guo L. H. *; Liu W. J. (本科生); Li K.; Sun M. M.; Sun W. T.; Zhao L. P.; Jiang G. R.; Peng H. W.; Liu Z. *; Dai S. Y.* Synthesis of functional and hyperbranched ethylene oligomers using unsymmetrical α-diimine palladium catalysts. European Polymer Journal 2019, 115, 185-192.

29Yang Y. J.; Ge, X. X.; Guo L. H. * (通讯); Zhu T.; Tian Z. Z.; Zhang H. R.; Du Q.; Peng H. W.; Ma W. L.; Liu Z. * Zwitterionic and Cationic Half-Sandwich Iridium(III) Ruthenium(II) Complexes Bearing Sulfonate Groups: Synthesis, Characterization and Their Different Biological Activity. Dalton Transactions 2019, 48, 3193-3197.

28Yang Y. L.; Guo L. H. * (通讯); Ge, X. X.; Tian Z. Z.; Gong Y. T.; Zheng H. M.; Du Q.; Zheng X. F.; Liu Z. * Novel lysosome-targeted cyclometalated iridium(III) anticancer complexes containing imine-N-heterocyclic carbene ligands: synthesis, spectroscopic properties and biological activity. Dyes and Pigments 2019, 161, 119-129. (Web of Science高被引论文

27Du Q.; Yang Y. L.; Guo L. H. * (通讯); Tian M.; Ge X. X.; Tian Z. Z.; Zhao L. P.; Xu Z. S.; Li J. J.; Liu Z. * Fluorescent half-sandwich phosphine-sulfonate iridium(III) and ruthenium(II) complexes as potential lysosome-targeted anticancer agents. Dyes and Pigments 2019, 162, 821−830. (Web of Science高被引论文

26Yang Y. L.; Guo L. H. * (通讯); Ge X. X.; Shi S. P.; Gong Y. T.; Xu Z. S.; Zheng X. F.; Liu Z. * Structure-activity relationships for highly potent half-sandwich organoiridium(III) anticancer complexes with C^N-chelated ligands. J. Inorg. Biochem. 2019, 1911-7.

25 Du Q.; Zhao L. P. (本科生); Guo L. H. * (通讯); Ge X. X.; Zhang S. M.; Xu Z. S.; Liu Z. * Lysosome-targeted Cyclometalated Iridium(III) Anticancer Complexes Bearing Phosphine-Sulfonate Ligands. Appl. Organometal. Chem. 2019, 33: e4746.


2018

24 Zhang, H. R.; Guo, L. H.*(通讯); Tian, Z. Z.; Tian, M.; Zhang, S. M.; Xu, Z. S.; Gong, P. W.; Zheng, X. F.; Zhao, J.; Liu, Z. * Significant effects of counteranions on the anticancer activity of iridium(III) complexes. Chem. Commun. 2018, 54, 4421-4424. (Web of Science高被引论文

23Yang Y. L.; Guo L. H. * (通讯); Tian Z. Z.; Gong Y. T.; Zheng H. M.; Zhang S. M.; Xu Z. S.; Ge X. X.; Liu Z.* Novel and versatile imine-N-heterocyclic carbene half-sandwich iridium(III) complexes as lysosome-targeted anticancer agents. Inorg. Chem. 2018, 57, 11087-11098.

22Du Q.; Guo L. H. * (通讯); Tian, M.; Ge X. X.; Yang Y. L.; Jian X. Y.; Xu Z. S.; Tian Z. Z.; Liu Z.* Potent Half-Sandwich Iridium(III) and Ruthenium(II) Anticancer Complexes Containing a P^O-Chelated Ligand. Organometallics 2018, 37, 2880-2889.

21Guo, L. H.; Lian, K. B.; Kong, W. Y. (本科生); Xu, S.; Jiang, G. R.; Dai, S. Y. * Synthesis of Various Branched Ultra-High-Molecular-Weight Polyethylenes Using Sterically Hindered Acenaphthene-Based αDiimine Ni(II) Catalysts. Organometallics 2018, 37, 2442-2449.

20Yang Y. L.; Guo L. H. * (通讯); Tian Z. Z.; Liu X. C.; Gong Y. T.; Zheng H. M.; Ge X. X.; Liu Z. * Imine-N-heterocyclic carbene as versatile ligands in ruthenium(II) p-cymene anticancer complexes: a structure-activity relationship study. Chem. Asian J. 2018, 13, 2923−2933. (Web of Science 热点论文

19Guo L. H. * (通讯); Liu, Y. L. (本科生); Lian, K. B.; Sun W. T.; Zhu H. X.; Du Q.; Liu Z. *; Chen X. Y.; Dai S. Y.* The Backbone Electronic Effects on Bis(imino)pyridyl Iron(II) Catalyzed Ethylene Polymerization. Eur. J. Inorg. Chem., 2018, 4887-4892.

18Guo L. H. * (通讯); Liu, Y. L. (本科生); Sun W. T.; Du Q.; Yang Y. L.; Kong W. Y.; Liu Z. *; Chen D. R. * Synthesis, characterization, and olefin (co)polymerization behavior of unsymmetrical α-diimine palladium complexes containing bulky substituents at 4-position of aniline moieties. J. Organomet. Chem., 2018, 877, 12-20.

17Guo, L. H. *(通讯); Kong, W. Y. (本科生); Xu, Y. J.; Yang, Y. L.; Ma, R.; Cong, L.; Dai, S. Y. *; Liu, Z. * Large-scale synthesis of novel sterically hindered acenaphthene-based α-diimine ligands and their application in coordination chemistry. J. Organomet. Chem., 2018, 859, 58-67.

16Song, G. Z.; Guo, L. H. *(通讯); Du, Q.; Kong, W. Y.; Li, W. M. *; Liu, Z. * Highly active mono and bis-ligated iminopyridyl nickel catalysts for 1-hexene reactions. J. Organomet. Chem., 2018, 858, 1-7.

15Guo, L. H.; Zhang H. R.; Tian M.; Tian Z. Z.; Xu Y. J.; Yang Y. L.; Peng H. W.; Liu P.; Liu Z. * Electronic Effects on Reactivity and Anticancer Activity by Half-Sandwich N, N-Chelated Iridium(III) Complexes. New J. Chem. 2018, 42, 16183-16192.

14Chen, J. H.; Guo, L. H. *(通讯); Ji, P. J.; Li, W. M. * Ring opening polymerization of ɛ-caprolactone using sterically bulky salicylaldimine Zn complexes. Polym. Bull., 2018, 75, 371-380.

13Sun W. T. (本科生); Kong W. Y. (本科生); Du Q.; Zhang S. M.; Guo, L. H.*(通讯); Liu Z. * 2,4-Bis[(2,6-diisopropylphenyl)imino]-3-methylpentan-3-ol. Molbank 2018, 2018(2), M995.


2017

12Guo, L. H.; Liu, W. J. (本科生); Chen, C. L. Late transition metal catalyzed α-olefin polymerization and copolymerization with polar monomers. Mater. Chem. Front., 2017, 1, 2487-2494. (Web of Science高被引论文,截至2020.9已引用109

11Li, W. Y.; Guo, L. H.*(通讯); Li, W. M. * Anilinotropone nickel catalyzed tandem ethylene oligomerization and Friedel-Crafts addition to toluene. Mol. Catal., 2017, 433, 122-127.

10Guo, L. H.; Zou, C.; Dai, S. Y.; Chen, C. L. Direct synthesis of branched carboxylic acid functionalized poly(1-octene) by α-diimine palladium catalysts. Polymers, 2017, 9, 122. (2019 Best Paper Award Winners

9Ji, P. J.; Guo, L. H.*(通讯); Hu, X. H.; Li, W. M. * Ethylene polymerization by salicylaldimine nickel(II) complexes derived from arylnaphthylamine. J. Polym. Res., 2017, 24, 30.

8Xiong, S. Y. (本科生); Guo, L. H. *(通讯); Zhang, S. M.; Liu, Z. * Asymmetric Cationic [P, O] Type Palladium Complexes in Olefin Homopolymerization and Copolymerization. Chin. J. Chem., 2017, 35, 1209-1221.


2016

7Guo, L. H.; Dai, S. Y.; Sui, X. L.; Chen, C. L. Palladium and nickel catalyzed chain walking olefin polymerization and copolymerization. ACS Catal., 2016, 6, 428-441. (Web of Sicence 热点论文,高被引论文,截至2020.9已引用243

6Guo, L. H.; Dai, S. Y.; Chen, C. L. Investigations of the ligand electronic effects on α-diimine nickel(II) catalyzed ethylene polymerization. Polymers, 2016, 8, 37.

5Guo, L. H.; Jing, X. Y. (本科生); Xiong, S. Y.; Liu, W. J.; Liu, Y. L.; Liu, Z.; Chen, C. L. Influences of Alkyl and Aryl Substituents on Iminopyridine Fe(II)- and Co(II)-Catalyzed Isoprene Polymerization. Polymers, 2016, 8, 389.


2010-2015

4Guo, L. H.; Chen, C. L. (α-Diimine)palladium catalyzed ethylene polymerization and (co)polymerization with polar comonomers. Sci. China Chem., 2015, 58, 1663-1673. (2015年度 Sci. China Chem.编辑部优秀论文奖,截至2020.9已引用105

3 Guo, L. H.; Gao, H. Y.; Guan, Q. R.; Hu, H. B.; Deng, J.; Liu, J.; Liu, F. S.; Wu, Q. Substituent effects of the backbone in α-diimine palladium catalysts on homo- and copolymerization of ethylene with methyl acrylate. Organometallics, 2012, 31, 6054-6062.

2Guo, L. H.; Gao, H. Y.; Li, L.; Wu, Q.Complexly Branched Polyolefin Generated from Controlled/Living Polymerization of 4-Methyl-1-Pentene Catalyzed by α-Diimine Palladium Catalyst” Macromol. Chem. Phys. 2011, 212, 2029-2035.

1 Guo, L. H.; Gao, H. Y.; Zhang, L.; Zhu, F. M.; Wu, Q. “Unsymmetrical Bis(imino)pyridyl Iron (II) Catalyst for Ethylene Polymerization: Effect of Bulky ortho-Substituent on Thermostability and Molecular Weight of Polyethylene” Organometallics 2010, 29, 2118-2125.


专利:

1郭丽华,高海洋,伍青,张 玲。一种吡啶二亚胺铁烯烃聚合催化剂及其制备方法与应用。2010,授权公告号:200810219416.7.

2郭丽华,刘哲,刘燕兰,刘文静。一种铁系催化剂及其制备方法及在异戊二烯聚合中的应用。2018,授权公告号:CN 106632764 B

3 郭丽华,刘哲等。一种具有抗癌活性的半三明治结构铱配合物及其制备方法、应用。 2019,授权公告号:CN 107652330 B

4郭丽华,刘哲等。一种具有抗癌活性的离子型铱配合物及其制备方法、应用。2019,授权公告号:CN 107652329 B

5郭丽华,刘哲等。一种苊基骨架大位阻α-二亚胺化合物及其合成方法。2020,授权公告号:CN107652206B

6 郭丽华,刘哲等。一种可靶向溶酶体的卡宾亚胺半三明治铱配合物及其制备方法、应用。2020,授权公告号:CN 108395457B

7 郭丽华,刘哲等。含有膦亚胺两齿螯合配体的铱抗癌配合物及其制备方法和应用。2021,授权公告号:CN109265488B

8郭丽华,杜青等。一种氨基亚胺铱配合物及其制备方法和应用。2020,授权公告号:CN109485679B

9 郭丽华,杨艳静等。一种两性离子型半三明治铱配合物及其制备方法和应用。2020,授权公告号:CN109503671B

10郭丽华,胡雪岩等。[N,N]阴离子配体的半三明治型配合物、中间体及其制备方法和应用2021,申请号:202110882323.8

11 郭丽华,胡雪岩等。膦亚胺两性离子型配合物及其配体、制备方法和应用2021,申请号:202110984926.9


会议论文:

1 郭丽华,高海洋,伍青。不对称取代吡啶亚胺铁催化剂催化乙烯聚合研究。全国高分子学术论文报告会,天津,2009

2郭丽华,孔文瑜,代胜瑜。苊基骨架大位阻二亚胺钯催化剂:基于弱相互作用调控聚烯烃的结构。全国高分子学术论文报告会,成都,2017


获奖:

1、 曲阜师范大学第九届青年教师教学比赛二等奖(独立)

2、 曲阜师范大学校级教学成果奖二等奖(首位)

3、 曲阜师范大学校级教学成果奖三等奖(首位)

4、 中国大学生高分子材料创新创业大赛优秀指导老师(独立)

5第八届高等教育省级(山东省)教学成果奖二等奖 (位次11

6曲阜师范大学微课教学比赛优秀奖(独立)

7曲阜师范大学201820192020,2021年度优秀研究生指导教师(独立)

8曲阜师范大学2018年度优秀科研工作者(独立)


指导学生获奖:

1、 第一届高校大学生海洋与化学科技实践论坛一等奖。

2、 第六届中国大学生高分子材料创新创业大赛二等奖。

3、 第四届山东省大学生科技创新大赛二等奖。

4、 第十六届“挑战杯”山东省大学生课外学术科技作品竞赛二等奖

52017,2018,2019,20202021年曲阜师范大学优秀学士学位论文。

62020年山东省优秀硕士论文。

72020年曲师大研究生学位论文科研创新资助基金。

8第二届“创青春”曲阜师范大学大学生创业大赛三等奖。

92019届校级优秀毕业研究生2人。

1020182020研究生国家奖学金2人次。

112020年山东省研究生优秀成果奖。


招生及学生培养:

每年拟招收硕士研究生1-2名、本科生科研训练学生5-8名、毕业论文学生10名。非常重视学生实验技能和学术能力培养,学生在本实验室可以系统获得有机合成、金属配合物合成和高分子合成等多方位的训练。指导的研究生获得国家奖学金、优秀研究生和圣地英才奖等多种奖励和荣誉。多名参加科研训练的本科生同学被保送或考取至清华大学、中科院应化所、中山大学、南京大学、东南大学、南开大学、吉林大学、北京理工大学、大连理工大学、山东大学、北京化工大学、华中科技大学、南京理工大学、中国石油大学、暨南大学等高校院所攻读研究生。欢迎勤奋有毅力、有独立思考能力、有责任心的优秀学生加入本组。


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